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HomeMy WebLinkAbout2005 - 204 East Airport DriveSoil and Groundwater Sampling and Testing (Intermediate Storage Tank Location) J &S Aviation Facility 204 East Airport Drive Sebastian, Florida DEP Facility I.D. No. 31/8509256 Ardaman & Associates, Inc. OFFICES ow Orlando, 8008 S. Orange Avenue, Orlando, 'Florida 32809, Phone (407) 855 -3860 Bartow, 1525 Centennial Drive, Bartow, Florida 33830, Phone (863) 533 -0858 Cocoa, 1300 N. Cocoa Blvd., Cocoa, Florida 32922, Phone (321) 632 -2503 Fort Lauderdale, 3665 Park Central Boulevard North, Pompano Beach, Florida 33064, Phone (954) 969 -8788 Fort Myers, 9970 Bavaria Road, Fort Myers, Florida 33913, Phone (941) 768 -6600 Miami, 2608 W. 84th Street, Hialeah, Florida 33016, Phone (305) 825 -2683 Port Charlotte, 740 Tamiarni Trail, Unit 3, Port Charlotte, Florida 33954, Phone (941) 624 -3393 Port St. Lucie, 460 Concourse Place NW, Unit 1, Port St. Lucie, Florida 34986, Phone (772) 878 -0072 Sarasota, 2500 Bee Ridge Road, Sarasota, Florida 34239, Phone (941) 922 -3526 Tallahassee, 3175 West Tharpe Street, Tallahassee, Florida 32303, Phone (850) 576 -6131 Tampa, 3925 Coconut Palm Drive, Suite 115, Tampa, Florida 33619, Phone (813) 620 -3389 West Palm Beach, 2511 Westgate Avenue, Suite 10, West Palm Beach, Florida 33409, Phone (561) 687 -8200 MEMBERS A.S. F E. American Concrete Institute American Society for Testing and Materials '� Florida Institute of Consulting Engineers Ardarnan & Associates, Inc. Geote,chn cal, Environmental and Materials Consultants August 8, 2005 File No. 05 -5426 The LPA Group Incorporated 12000 Research Parkway Suite 152 Orlando, Florida 32826 -3287 Attention: Mr. Mark Jansen Subject. Soil and Groundwater Sampling and Testing ' Intermediate Storage Tank Location J & S Aviation Facility 204 East Airport Drive Sebastian, Florida DEP Facility I.D. No. 31/8509256 Dear Mr. Jansen: As requested, Ardaman & Associates, Inc. (A &A) has completed soil and groundwater sampling and testing at the above - referenced subject site. The purpose of this study was to obtain soil and groundwater contamination data at the intermediate above - ground fuel storage tank location on the subject site. This data report documents our field and laboratory programs and presents the results of our assessment. SITE LOCATION AND DESCRIPTION The subject site is the J & S Aviation facility located at 204 East Airport Drive in Section 1, Township 31 South, Range 38 East, in Sebastian, Indian River County, Florida. The site location is superimposed on the Sebastian, Florida USGS quadrangle map included as the Site Location Map, Figure 1. The subject site is developed with the J & S Aviation facility (DEP Facility I.D. No. 3118509256). The soil and groundwater sampling and testing activities were performed at the location of an intermediate 10,000 - gallon above - ground aviation fuel storage tank on the site. FIELD EXPLORATION AND SAMPLING PROGRAM Our field program for this soil and groundwater sampling and testing program consisted of: 1) conducting two hand auger borings on the subject site to obtain soil contamination and soil stratigraphy data, 2) performing soil -gas analysis on the soil samples obtained from the borings, 3) installing one shallow 2 -inch diameter PVC temporary groundwater sampling well at the site, and 4) obtaining groundwater samples from the well for laboratory analysis after developing the well. Our field program was conducted on July 20, 2005. The borings conducted on the subject site, AB -1 and AB -2, were conducted at the approximate center and near the north end of the former intermediate above- ground storage The LPA Group Incorporated File No. 05 -5426 -2- tank location, respectively, as shown on the Sample Location Plan included as Figure 2. s Auger Borings AB -1 and AB -2 were advanced to a depth of 5 feet below land surface (bls), using a 3 -inch diameter hand -held bucket auger. The boring locations, as shown on Figure 2, were determined in the field by estimating distances from existing site features and should be considered accurate only to the degree implied by the method of measurement used. Soil samples from the borings for soil -gas analysis were obtained from the auger at approximate two -foot intervals. The samples were placed in new 36 -ounce sample jars (half filled). The gas in the headspace above the soil in the jars was analyzed with and without a carbon filter using a Foxboro Organic Vapor Analyzer (OVA), Model 128, Serial Number 40751. The meter on the OVA was visually monitored and the maximum reading obtained over a 15 -20 second time increment was recorded. While in the survey mode, the OVA is calibrated to 95 parts per million methane in air, and zero air. Representative soil samples were collected during our field operations for visual examination and classification of the soil stratigraphy. The resulting soil descriptions are shown on the Soil Boring Logs included in Appendix I. A soil sample, SS -1 on Figure 2, was obtained from a depth of 1.5 feet bls at the location of Boring AB -1. The sample was obtained using the syringe method, preserved on ice, and transported to the analytical laboratory for testing. Temporary Monitoring Well TMW -1 was installed in the borehole of AB -1 to obtain groundwater samples for laboratory analyses. TMW -1 was installed to a depth of approximately 5.5 feet bls and was screened from the ground surface to approximately 5 feet b1s. The water table was encountered at a depth of approximately 3 feet bls in TMW -1 on the day of our field exploration. Over three well volumes were purged from TMW -1 with a parastaltic pump prior to obtaining groundwater samples. Near- surface groundwater samples were collected from TMW -1 for laboratory analysis of FAC Chapter 62 -770 Table B parameters. A copy of the Groundwater Sampling Log for TMW -1 is included in Appendix 11. TEST RESULTS AND CONCLUSIONS The encountered soils and the results of the soil -gas analyses are presented on the Soil Boring Logs in Appendix I. The soils encountered in the borings were primarily gray and brown fine sands. The net OVA reading for each sample shown in Appendix I was obtained by subtracting the OVA reading obtained with the carbon filter (filtered reading) from the unfiltered OVA reading. As shown in Appendix I, no net OVA readings above background levels were exhibited by the soil samples obtained from Borings AB -1 and AB -2. A soil sample (SS -1) was obtained from a depth of 1.5 feet bis at the location of Boring AB -1. Soil analytical results for SS -1 are included in Appendix 111. As shown in Appendix III, no FAC Chapter 62 -770 Table B parameter concentrations above test detection limits were detected in Sample SS -1. The soil samples obtained from the borings did not exhibit an obvious chemical -type odor or obvious signs of petroleum staining. Groundwater analytical results are also included in Appendix III. No FAC Chapter 62 -770 Table B parameters above test detection limits, with the exceptions of lead and The LPA Group Incorporated File No. 05 -5426 -3- chloromethane, were detected in the samples obtained from Well TMW -1. Total lead was detected at a concentration of 4 µg/e, which is below the Groundwater Cleanup Target Level (GCTL) for lead (15 ,ogle). Chloromethane was also detected at a concentration of 2.7 Mgly in TMW -1. This concentration is not above the GCTL for chloromethane (2.7 ugle). In conclusion, no evidence of contamination above cleanup levels was detected in near - surface soil and groundwater samples taken in the vicinity of the former intermediately- located above - ground fuel storage tank location on the site. The client or owner's representative should submit this report and any other additional pertinent information (removal form from certified petroleum contractor, manifests, etc.) to the Indian River County Health Department and the DEP Central District. CLOSURE This report presents the results of Ardaman & Associates, Inc.'s soil and groundwater sampling and testing program, as described herein, and is intended only for use by The LPA Group Incorporated. It was prepared in accordance with our agreement for consulting services. The analyses and conclusions submitted in this report are based on the data obtained from our field program, as discussed in this report. This study is a focus study limited to the specific methods of investigation. Soil and groundwater contamination results would only be applied to the diameters of depths of the boreholes and well on the date tested. Our scope of work for this phase of the project was designed to preliminarily test the site relative to the topic stated above. It has been a pleasure assisting you with this project. Should you have any questions regarding this report, or if we may be of any further assistance, please contact us. Very truly yours, ARDAMAN & ASSOCIATES, INC. fnP. Dan J. llac J ing, P.E. Assistant Project Engineer Branch Manager DJZIJPMIpt/bah 05 -5426 Soil and Groundwater sampling and Testing (Reports #72) 00 0 C(�4 -- J 0 1— a hh rr K dand r.. nnyBeatcn `3 ' FLEMIVG GRANT I' T 30 S ` 31 S i tr APPROXIMATE �! w SITE LOCATION ` \ X, "sib l�l Ch Vuirq , r A M 0 1DOO 2000 SCALE — 1" -2000' SECTION 1 TOWNSHIP 31 SOUTH RANGE 38 EAST OBTAINED FROM U.S.G.S_ QUAD MAP: SEBASTIAN, FLORIDA 1949 (PHOTOREVISED 1970) 3 1 SITE LOCATION MAP �IIIIII Arclarnan dL Associates, Inc. Gsotschnical, Emironmantal and 14atsrlals Consultants SOIL AND GROUNDWATER SAMPLING AND TESTING FLOMDA J&S AVIATION FACILITY IN'TERMEDIAT'E STORAGE TANK LOCATION 204 EAST AIRPORT DRIVE SEBASTUw, FLORIDA QUADRANGLE LOCATION 0n nr. TAT aBRan M' DAM 8/5/05 FU KU 0.5-5426 Acs 1 as 0 O O 0 C) �j CL CL v SIRE IN PER ACCIESSISLZE WALKVAY W41.`H - DErEC7ABLE WARNINGS 10 A_R Z-A R APPROXIMATE PREVIOUS LOCATION OF INTERMEDIATE' ABOVE—GROUND FUEL TANK C014NECT TO EX!SnNG 41 103 AB-2 _77 4• L.. •5* 9cp 199' ROB'— R ROW I N NOT TO SCALE LEGEND 4() AB AUGER BORING LOCATION TMIW TEMPORARY MONITOR WELL LOCATION FA APPENDIX I Soil Boring Logs am OR 4W Oft a. Florida Department of Environmental Protection - Division of Waste Management - Bureau of Petroleum Storage Systems BORING LOG Page 1 of 2 BoringfWell Number. Permit Number: FDEP Facility Identification Number: A 13-1 31/8509256 Site Name: Borehole Start Date: Q7120/05 Borehole Start Time: r AM r PM Former J &S Aviation Site End Date: 07/20/05 End Time: r AM Ci PM Geologist's Name: Environmental Technician's Name: Environmental Contractor: Ardaman and Associates, Inc. Tom Taylor Drilling Company: Pavement Thickness (inches): Borehole Diameter (inches): Borehole Depth (feet): 3 5 Drilling Method(s): Apparent Borehole DTW (in feet Measured Well DTW (in tent after OVA (list model and check type): Hand Auger from soil moisture content): 2.3 water recharges in well): —y Foxboro 128 17 r J FID 1 P1D Disposition of Drill Cuttings [check method(s)]: ❑ Drum [ Spread r Backfill ❑ Stockpile E, Other (describe ifother or multiple items are checked), Borehole Completion (check one): ❑ Well ® Grout r7 Bentonite W Backfill r Other (describe) w U oil �* t7 n, o " Lab Soil and ro . , `0 + •0 Z - Sample Description Groundwater ,S (include grain size based on USCS, odors, staining, Cr Samples (list sample "1 10 C7 =, C. a ro eb re o n c T y p Q O y , , ro n_ and other remarks) .1 B o w number and depth or temporary screen ro > fD interval) a HA 1 <10 <10 <10 Light Brown Clayey Fine Sand, no obvious odor or SC D SS -1 @ 1.5' I staining HA 1 Gray Fine Sand, no obvious odor or staining SP M 2 HA 1 <10 <10 <10 Gray Fine Sand, no obvious odor or staining SP W 3 HA 1 Brown Fine Sand, no obvious odor or staining SP W 4 HA 1 <10 <10 <10 Dark Brown Fine Sand, no obvious odor or staining SP W 5 6 7 } I0 ll 12 WM Sample Type Codes: PH = Post Hole; HA = Hand Auger; SS = Split Spoon; ST = Shelby Tube; DP = Direct Push; SC = Sonic Core; DC= Drill Cuttings Moisture Content Codes: D = Dry; M = Moist; W = Wet; S = Saturated MIA .r am Florida Department of Environmental Protection - Division of Waste Management - Bureau of Petroleum Storage Systems BORING LOG Page 2 of 2 Boring/Well Number: Permit Number: FDEP Facility Identification Number: AB -2 31/8509256 Site Name: Borehole Start Date: 07/20/05 Borehole Stari Tim : AM r PM Former J &S Aviation Site End Date: 07/20/05 End Time: rl AM 1-1 PM Geologist's Name: Environmental Technician's Name: Environmental Contractor: Ardaman and Associates, Inc. Tom Taylor Drilling Company: Pavement Thickness (inches): Borehole Diameter (inches): Borehole Depth (feet ): 3 5 Drilling Method(s): Apparent Borehole DTW (in feet Measured Well DTW (in feet after OVA (list model and check type): Hand Auger rmm soil moisture content): 2.3 water recharges in well): Foxboro 128 r FID F PID Disposition of Drill Cuttings [check method(s)]: Drum r Spread G Backfill � i Stockpile r Other (describe if other or multiple items are checked): Borehole Completion (check one): ❑ Well rl Grout ❑ Bentonite F Backfill F7 Other (describe) to 5 M7 C y, Lab Soil and B B = '_' `ti �' o Sample Description f� Groundwater n m ;o n py m rb +* p w. r^ (include grain size based on USCS, odors, staining, W A Samples (lint sample tV _• Q. O and other remarks) number and depth or r, y O Q temporary screen es H v Y a r p Interval) Light Brown Clayey Fine Sand, no obvious odor or HA 1 <14 <14 <14 staining 5C D HA 1 Gray Fine Sand, no obvious odor or staining SP M HA 1 <10 <10 <14 Gray Fine Sand, no obvious odor or staining SP W HA 1 Brown Fine Sand, no obvious odor or staining SP W HA 1 <10 <10 <10 Dark Brown Fine Sand, no obvious odor or staining SP W S G J s 9 10 11 12 .M Sample Type Codes: PH = Post Hole; HA = Hand Auger; SS = Split Spoon; ST = Shelby Tube; DP = Direct Push; SC = Sonie Core; DC= Drill Cuttings Moisture Content Codes: D = Dry; M = Moist; W = Wet; S = Saturated APPENDIX II Groundwater Sampling Log .rt am om w ow M 1 FLO A 4 Petroleum or Petroleum Products Water Sampling Log DEP Fomi p 02- 770.9M31 Form Title: Pecralaim or Perolcum Products Wow Sammiine LQg Eff ctive Daic. Seam ber 23.1997 FDEP FACILITY NO,: 31/8509256 WELL NO.: TMW -I I SAMPLE ID: TMW -1 I DATE: 7/20105 SITE NAME: J &S Aviation I SITE LOCATION: 204 East Airport Drive, Sebastian, Florida PURGE DATA WELL DIAMETER (in); 2 TOTAL WELL DEPTH (ft): 5.5 DEPTH TO WATER (11): 2.3 WELL CAPACITY (gal/ft): 0.163 1 WELL VOLUME (gal) = (TOTAL WELL DEPTH — DEPTH TO WATER) x WELL CAPACITY = _( 5.5 — 2.3 )x .163 a 0.5216 PURGE METHOD: Peristaltic Pump PURGING INITIATED AT: 10:20 am PURGING ENDED AT: 10:30 am WELL VOLS. PURGED CUMUL. VOLUME PURGED (gal) PH TEMP. aC COND. mhos PURGE RATE m : varies TOTAL VOLUME PURGED (gal): 1.5 COLOR ODOR APPEARANCE OTHER 0.5 gal 0.5 gal 6.0 32 490 Light Brown None Light Brown — 0.5 gal I gal 6.5 34 421 Light Brown None Light Brown — 0.5 gal 1.5 gal 6.3 34 415 Light Brown to Clear None Light Brown to Clear --- NOTE: this does not constitute all the information required by Chapter 62 -160, F.A.C. SAMPLING DATA SAMPLED BY 1 AFFILIATION Tom Taylor f Ardaman and Associates, Inc. SAMPLER(S) SIGNATURE (S) SAMPLING METHOD(S): Peristaltic pump — backflow method SAMPLING INITIATED AT: 10:34 am SAMPLING ENDED AT: 10:37 am FIELD DECONTAMINATION: Yes FIELD- FILTERED: No DUPLICATE: No SAMPLE CONTAINER SPECIFICATIONS SAMPLE PRESERVATION INTENDED ANALYSIS AND /OR METHOD ��� MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOLUME ADDED IN FIELD (ml)�I[ FI \:e1, REMARKS: MATERIAL CODES: AG = AMBER GLASS; CG = CLEAR GLASS; HDP = HIGH DENSITY POLYETHYLENE; O = OTHER SPECIFY WELL CAPACITY: 1.25" = 0.06 al/ft; 2" = 0.16 al/ft; 4" = 0.65 aUft; 6" = 1.47 al/ft; S" = 2.61 al /ft; 12" = 5.88 al /ft NOTE: this does not constitute all the information required by Chapter 62 -160, F.A.C. APPENDIX III Soil and Groundwater Analytical Results PC &B Environmental Laboratories, Inc. 210 Park Road, Oviedo, Florida 32765 Z4�- �' Phone: 407-359-7194 Fax: 407-359-7197 Client: Ardaman & Associates Contact: Dan Zrallack 1300 N. Cocoa Blvd. Phone : (321) 632 -2503 Cocoa, FL 32922 - Laboratory Reference Number : 205070222 Project Name : SEB Airport Project Number: 05 5426 Chain of Custody: Sample temperature at time of receipt: 3 degrees C Laboratory ID Matrix Client ID Status DatelTime Sampled 205070222 -1 Water TMW -1 RUN 07/20/2005 205070222 -3 Soil AB- 1lSS -f RUN 07/20/2005 Number Parameter Description 2 Group Test FAC 62 -770 Table B 2 EPA 504 /504.1 EDB /DBCP 2 EPA 8310 PAH's by HPLC 2 FL -PRO Petroleum Hydrocarbons 2 EPA 8021 by 8260 Volatile Organics 2 EPA 60101200.7 Lead by ICAP PC &B Environmental Laboratories, Inc. 210 Park Road Oviedo, FL 32765 -8801 407- 359 -7194 - (FAX)407-359-7197 Case Narrative Dan Zrallack Ardaman & Associates 1300 N. Cocoa Blvd. Cocoa, FL 32922- CASE NARRATIVE for Work Order: 205070222 Project Number: 05 5426 Project Name: SEB Airport This Case Narrative is a summary of events and /or problems encountered with this Work Order. For samples requesting EPA 601/602/8021 analysis, the GCMS method EPA 624/8260 was substituted in order to generate the highest quality data possible at no additional cost. Definition of Flaos A = Value reported is an average of 2 or more determinations DL = No surrogate result due to dilution or matrix interference. H = Value based on field kit determination, results may not be accurate I = The reported value is between MDL and PQL J = Estimated Value, value not accurate. J1 = Estimated value surrogate limits have been exceeded J4 = Estimated value matrix interference K = Off scale low L = Off-scale high. Actual value is greater than value given. Above calibration curve. M = Presence of material is verified but not quantified. Should be tab PQL N = Presumptive evidence of presence of material Q = Sample analyzed beyond the accepted holding time. T = Value less than the lab MDL T2 = Analysis from an unpreserved or improperly preserved sample V = Analyte was both detected in the method blank and sample. Y = Analysis from an unpreserved or improperly preserved sample am PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road Volatile Organics PROJECT NAME: SEB Airport .. Oviedo, FL 32765 -6801 PROJECT NUMBER: 05 5426 PHONE: 407- 359 -7194 DATE RECEIVED: 07/2612005 FAX: 407 -359 -7197 ANALYTICAL PROTOCOL: EPA 8021 by 8260 Lab Reference Number 205070222 -1 Client Sample 1D TMW -1 DatelTime Sampled 07120/2005 DatefTime Extracted 07126/2005 DatelTime Analyzed 07/2612005 14 :27 Sample Matrix (as Received) Water Analysis Confirmed GCMS Dilution Factor 1 Result Units ugn Benzene 1.0 U Bromobenzene 1.0 U Bromochloromethane 1.0 U Bromodichloromethane 0.3 U Bromoform 1.0 U Bromomethane 1.0 U n- Butylbenzene 1.0 U sec - Butylbenzene 1.0 U tert- Butylbenzene 1.0 U Carbon tetrachloride 1.0 U s Chlorobenzene 1.0 U Chloroethane 1,0 U Chloroform 1.0 U Chloromethane 2,7 2- Chlorotoluene 1.0 U 4- Chlorotoluene 1.0 U Dibromochloromethane 0.2 U Dibromomethane 1.0 U �. 1,2- Dichlorobenzene 1,0 U 1,3- Dichlorobenzene 1.0 U 1,4- Dichlorobenzene 1.0 U Dichlorodifluoromethane 1.0 U MR 1,1- Dichloroethane 1.0 U 1,2- Dichloroethane 1.0 U 1,1- Dichloroethene 1.0 U cis -1,2- Dichloroethene 1.0 U mm trans -1 ,2- Dichloroethene 1.0 U 1,2- Dichloropropane 1.0 U 1,3- Dichloropropane 1.0 U 2,2- Dichloropropane 1.0 U 1,1- Dichloropropene 1.0 U 1,3- Dichloropropene (cis) 0.2 U 1,3- Dichloropropene (trans) 0.3 U Ethytbenzene 1.0 U Hexachlorobutadiene 0,5 U lsopropylbenzene 1.0 U p- Isopropyltoluene 1.0 U Methylene chloride 1.0 U Naphthalene 1.0 U n- Propylbenzene 1.0 U Styrene 1,0 U 1,1,1,2 - Tetrachloroethane 0.2 U 1,1,2,2- Tetrachloroethane 0.2 U Tetrachloroethene 1.0 U Toluene 1.0 U 1,2,3- Tdchlorobenzene 1.0 U 1,24- Ticchlorobenzene 1,0 U 1,1,1 - Trichloroethane 1.0 U 1,1,2 - Trichloroethane 1.0 U Trichloroethane 1.0 U Trichlorofluoromethane 1.0 U 1,2,3- Tdchloropropane 0.2 U 1,2,4- Trimethylbenzene 1.0 U 1,35- Trimethylbenzene 1.0 U Vinyl chloride 1.0 U no am am on am M MR rn sue, AM aft MM no PC &B Environmental Laboratories, Inc. 210 Park Road Report of Analysis CLIENT NAME: Ardaman & Associates Oviedo, FL 32765 -8801 Volatile Organics PROJECT NAME: SEB Airport PHONE: 407 -359 -7194 71 PROJECT NUMBER: 05 5426 FAX: 407- 359 -7197 (Burr) 4- Bromofluorobenzene {°h) DATE RECEIVED: 07126/2005 ANALYTICAL PROTOCOL: EPA 8021b s26a Lab Reference Number 205070222 -1 Client Sample ID TMW -1 Date/Time Sampled 07/20/2005 DatefTime Extracted 07/26/2005 DatefTime Analyzed 07126/2005 14 :27 Sample Matrix (as Received) Water Analysis Confirmed GCMS Dilution Factor 1 Result Units uq /l MTBE 5.0 U m & p- Xylene 1.0 U 1,2- Dibromoethane 1.0 U o- Xylene 1.0 U (Surr) f ,2 -Dichloroethane -d4 N 71 (Burr) Toluene -d8 ( %) 121 (Burr) 4- Bromofluorobenzene {°h) 93 U =Undetected. The value preceeding the'U' is the RL for the analyte, based on dilution. Results reported on a Wet Weight basis. NELAP- FDOH Certification # E83239 Reviewed by Quality Control Report for Spike /Spike Duplicate Analysis Louver Upper Volatile Organics Limit Matrix: Water Benzene 63 141 Analysis Date: 07/2612005 Carbon tetrachloride Lab Sample ID: MW -MS 142 14 Chlorobenzene Preparation Date: 07/2612005 136 QC Batch ID: 200507MS2047 1,4- Dichlorobenzene 66 137 Method: EPA 8260 1,1- Dichloroethene Spike Units: ugll 142 15 Ethylbenzene Analyst: KN 133 15 Toluene 64 137 Spike MSD Trichooroethene 61 Spike Sample Spike Percent MSD Percent 135 Analyte Amount Result Result Recovery Result Recovery RPD Benzene 50.0 0.0 45.0 90 45.0 90 0 Carbon tetrachloride 50.0 0.0 44.0 88 44,0 88 0 Chlorobenzene 50.0 0.0 48.0 96 48.0 96 0 1,4- Dichlorobenzene 50.0 0.0 48.0 96 49.0 98 2 1,1- Dichloroethene 50.0 0.0 47.0 94 48.0 96 2 Ethylbenzene 50.0 0.0 52.0 104 53.0 106 2 Toluene 50.0 0.0 48,0 96 49.0 98 2 Trichloroethene 50.0 0.0 49.0 98 48.0 96 2 -• m & p- Xylene 100.0 0.0 107.0 107 104.0 104 3 o- Xylene 50.0 0.0 53.0 106 52.0 104 2 Quality Control Limits PC &t3 Environmental Laboratories, Inc. LabForrns LIMS Louver Upper Analyte Limit Limit RPD Benzene 63 141 14 Carbon tetrachloride 59 142 14 Chlorobenzene 66 136 13 1,4- Dichlorobenzene 66 137 18 1,1- Dichloroethene 51 142 15 Ethylbenzene 66 133 15 Toluene 64 137 16 Trichooroethene 61 143 17 rn & p- Xylene 62 135 17 o- Xylene 56 139 15 PC &t3 Environmental Laboratories, Inc. LabForrns LIMS PC &B Environmental Laboratories, Inc, Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road Volatile Organic Aromatics PROJECT NAME: SEB Airport Oviedo, FL 32765.8801 PROJECT NUMBER: 055426 PHONE: 407- 359 -7194 DATE RECEIVED: 07/26/2005 FAX 407- 359 -7197 ANALYTICAL PROTOCOL: VOA By EPA 8260 Lab Reference Number 205070222 -3 Client Sample ID AB -1 l;�S —� DatelTime Sampled 07/20/200 DatefTime Extracted 07/2612005 Date/Time Analyzed 07!2612005 13:32 Sample Matrix (as Received) Soil Analysis Confirmed GCMS Dilution Factor .53 Percent Moisture 23.0 Result Units uglkg Benzene 3 U Chlorobenzene 3 U 1,2- Dichlorobenzene 3 U 1,3- Dichlorobenzene 3 U 1,4- Dichlorobenzene 3 U Ethylbenzene 3 U MTBE 3 U Toluene 3 U Xylenes, Total 3 U ^"+ (Surr) 1,2- Dichloroethane -d4 ( %) 84 (Surr) Toluene -d8 (%) 58 (Surr) 4- Bromofluorobenzene 98 am dM U =Undetected. The value Reviewed by: the 'U' is the RL for the anal e, based on dilution. Results reported on a Dry Weight basis. /i NELAP- FDOH Certification # E83239 Quality Control Report for Spike /Spike Duplicate Analysis —^ PC&B Environmental Laboratories, Inc. LabForms LIMS Aromatic Volatile Organics Matrix: Soil Analysis Date: 0712612005 Lab Sample ID: SOIL-MS Preparation Date: 07/2612005 QC Batch ID: 200507MS3048 Method: EPA 8260 Spike Units: uglkg Analyst: KN Spike MSD Spike Sample Spike Percent MSD Percent Analyte Amount Result Result Recovery Result Recovery RPD Benzene 50 0 59 118 58 116 2 Ethylbenzene 50 0 56 112 55 110 2 MTBE 50 0 51 102 51 102 0 Toluene 50 0 57 114 57 114 0 Xylenes, Total 150 0 163 109 161 107 1 Quality Control Limits _ Lower Upper Analyte Limit Limit RPD Benzene 54 142 6 Ethylbenzene 64 137 8 MTB E 56 144 10 Toluene 56 143 8 Xytenes, Total 68 134 7 —^ PC&B Environmental Laboratories, Inc. LabForms LIMS PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road PAH's by HPLC PROJECT NAME: SEB Airport ^, Oviedo, FL 32765 -8801 PROJECT NUMBER: 055426 PHONE: 407 -359 -7194 DATE RECEIVED: 07126/2005 FAX: 407 -359 -7197 ANALYTICAL PROTOCOL: EPA 8310 Lab Reference Number 205070222 -1 Client Sample ID TMW -1 Date/Time Sampled 07/20/2005 Date/Time Extracted 07/27/2005 Date/Time Analyzed 07128/2005 14:09 Sample Matrix (as Received) Water Analysis Confirmed No Dilution Factor 1 Result Units ugfl Acenaphthene 0.52 U Acenaphthylene 0.45 U Anthracene 0.02 U Benzo(a)anthracene 0.02 U Benzo(a)pyrene 0.03 U Benzo(b)fluoranthene O.01 U Benzo(ghi)peryfene 0,05 U Benzo(k)Auoranthene 0 "02 U Chrysene 0.03 U Dibenzo(ah)anthracene 0.20 U Fluoranthene 0.03 U Fluorene 0.14 U Indeno (1,2,3 -c,d) pyrene 0.04 U Naphthalene 0.29 U 1- Methyl naphthalene O.12 U 2- Methyl naphthalene 017 U Phenanthrene 0.06 U Pyrene 0.08 U (Surr) Decafluorobiphenyl (0k) 41 er r� Mft U =Undetected. The value preceeding the 'U' is the RL for the anal e, based on dilution. Results re orted on a Wet Weight basis. NELAP- FDOH Certification # E83239 Reviewed by 4 �R Quality Control Report for LCS Analysis PAH's by HPLC Matrix: Water Analysis Date: 07/28/2005 Lab Sample ID: LCS Preparation Date: 07/27/2005 QC Batch ID: 200507PAH089 Method: EPA 8310 LCS Units: ug /l Analyst: RM Lower Upper LCS LCS Percent control Control Analyte Conc Result Recovery Limit Limit Acenaphthene 50.0 48.0 96 21 130 Acenaphthylene 25.0 25.3 101 28 129 Anthracene 1.0 0.7 74 30 135 Benzo(a)anthracene 2.5 2.2 88 40 127 Benzo(a)pyrene 2.5 2.5 100 23 135 Benzo(b)fluoranthene 1.0 1.0 100 22 141 Benza(ghi)perylene 4.0 3.9 98 25 135 Benzo(k)fluoranthene 1.0 0.9 92 27 136 Chrysene 2.5 2.5 100 29 131 Dibenzo(ah)anthracene 10.0 9.7 97 19 143 Fluoranthene 2.5 1.9 75 33 127 Fluorene 5.0 4.1 81 26 131 indeno (1,2,3 -c,d) pyrene 2.5 2.9 115 28 140 Naphthalene 25.0 27.5 110 18 137 Phenanthrene 2.5 2.4 96 24 134 Pyrene 5.0 4.4 88 24 138 PC &B Environmental Laboratories, Inc. LabForms LIMS PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road Polynuclear Aromatic Hydrocarb PROJECT NAME: SEB Airport Oviedo, FL 32765 -8801 PROJECT NUMBER: 05 5426 PHONE: 407 -359 -7194 DATE RECEIVED: 07/2612005 FAX: 407 - 359 -7197 ANALYTICAL PROTOCOL: EPA 8100 Lab Reference Number 205070222 -3 Client Sample ID AB -1 /j3 DatefTime Sampled 07/20/2005 Date/Time Extracted 08/0112005 DateMme Analyzed 08/0112005 15:59 Sample Matrix (as Received) Soil Analysis Confirmed No Dilution Factor 1 Percent Moisture 23.0 Result Units ug/kg Acenaphthene s 91 U Acenaphthylene 91 U Anthracene 91 U Benzo(a)anthracene 91 U Benzo(a)pyrene 91 U Benzo(b)fluoranthene 91 U Benzo(ghi)perylene 91 U Benzo(k)fluoranthene 91 U Chrysene 91 U Dibenzo(ah)anthracene 91 U Fluoranthene 91 U Fluorene 91 U Indeno(123- cd)pyrene 91 U Naphthalene 91 U 1- Methyl naphthalene 91 U 2- Methyl naphthalene 91 U Phenanthrene 91 U Pyrene 91 U (Surr) 2- Fluorobiphenyl { °5) 85 On dft .. A. am .. U = Undetected. The value preceeding the'U' is the RL for the anal e, based on dilution, Results reported on a D Weight basis. NELAP- FDOH Certification # E83239 r Reviewed by: Quality Control Report for Spike /Spike Duplicate Analysis Quality Control Limits Polynuclear Aromatic Hydrocarbons Upper Matrix: Soil Limit Limit RPD Analysis Date: 0810112005 50 Lab Sample ID: 205070294 -2 15 Acenaphthene 30 Preparation Date: 08/0112005 10 QC Batch ID: 200508PAH003 30 138 12 Method: EPA 8100 169 Spike Units: uglkg Benzo(a)anthracene 30 153 Analyst: RM Benzo(a)pyrene 40 162 12 Benzo(b)fluoranthene 40 Spike MSD Benzo(ghi)perylene 35 Spike Sample Spike Percent MSD Percent 15 Analyte Amount Result Result Recovery Result Recovery RPD (Surr) 2- Fluorobiphenyl 100 0 55 55 58 58 5 Acenaphthene 50 0 56 112 57 113 1 Acenaphthylene 50 0 54 108 54 109 1 Anthracene 50 0 36 72 36 71 1 Senzo(a)anthracene 50 0 43 85 45 90 6 Senzo(a)pyrene 50 0 44 87 44 88 1 Benzo(b)fluoranthene 50 0 45 90 46 92 2 Benzo(ghi)perylene 50 0 46 92 47 93 2 Benzo(k)fluoranthene 50 0 45 90 46 92 2 Chrysene 50 0 51 102 49 97 5 Dibenzo(ah)anthracene 50 0 45 91 46 92 2 Fluoranthene 50 0 51 101 51 102 1 Fluorene 50 0 56 112 55 109 2 Indeno(123- cd)pyrene 50 0 45 91 46 92 2 Naphthalene 50 0 52 104 52 105 1 Phenanthrene 50 0 55 109 56 112 2 -- Pyrene 50 0 50 101 51 102 1 Quality Control Limits PC &B Environmental Laboratories, Inc. LabForms LIMS Lower Upper Analyte Limit Limit RPD SS_2- Fluorobiphenyl 50 157 15 Acenaphthene 30 148 10 Acenaphthylene 30 138 12 Anthracene 25 169 15 Benzo(a)anthracene 30 153 15 Benzo(a)pyrene 40 162 12 Benzo(b)fluoranthene 40 163 13 Benzo(ghi)perylene 35 169 14 Benzo(k)fiuoranthene 30 155 15 Chrysene 35 155 12 Dibenzo(ah)anthracene 40 157 10 Fluoranthene 45 146 15 Fluorene 30 140 12 Indeno(123- cd)pyrene 35 156 14 ° Naphthalene 35 138 15 Phenanthrene 40 144 15 Pyrene 45 146 15 PC &B Environmental Laboratories, Inc. LabForms LIMS no P" ■r Mo re MR .., o.. U = Undetected. The value preceeding the 'U' is the RL for the anal e, based on dilution. Results reported on a Wet Weight basis. NELAP- FDOH Certification # E83239 � rrI� Reviewed by: i U 1. PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road Petroleum Hydrocarbons PROJECT NAME: SEB Airport Oviedo, FL 32765 -8801 '~ PROJECT NUMBER: 05 5426 PHONE: 407 -359 -7494 DATE RECEIVED: 07/26/2005 FAX: 407 - 359 -7197 ANALYTICAL PROTOCOL: FL -PRO Lab Reference Number 205070222 -1 Client Sample lD TMW_1 Date/Time Sampled 07/20/2005 Date/Time Extracted 07/27/2005 11:00 Date/Time Analyzed 07/2812005 16:43 Sample Matrix (as Received) Water Analysis Confirmed No Dilution Factor 1 Result Units mgA Total PHS 0.3 U (Surr) C -39 (%) 41 J1 (Surr) OTP ( %) 63 J1 no P" ■r Mo re MR .., o.. U = Undetected. The value preceeding the 'U' is the RL for the anal e, based on dilution. Results reported on a Wet Weight basis. NELAP- FDOH Certification # E83239 � rrI� Reviewed by: i U 1. "" PC &B Environmental Laboratories, Inc. LabForms LIMS Quality Control Report for LCS Analysis Petroleum Hydrocarbons Matrix: Water Analysis Date: 0810/12005 Lab Sample ID: LCS Preparation Date: 0810112005 QC Batch ID: 200507FLROO88 Method: FL-PRO LCS Units: mg11 Analyst: DN Lower tipper LCS LCS Percent Control Control Analyte Conc Result Recovery Limit Limit _ (Surr) C -39 100,0 51.0 51 42 193 (Surr) OTP 100.0 84.0 84 82 142 Total PHS 50.0 57.0 114 55 118 "" PC &B Environmental Laboratories, Inc. LabForms LIMS an PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road Petroleum Hydrocarbons PROJECT NAME: SEB Airport Oviedo, FL 32765-3801 PROJECT NUMBER: 055426 PHONE: 407- 359 -7194 DATE RECEIVED: 07126!2005 FAX: 407 -359 -7197 ANALYTICAL PROTOCOL: FL -PRO Lab Reference Number 205070222 -3 Client Sample ID AB -1 fay Date/Time Sampled 07/201200 Date/Time Extracted 08101/2005 15:00 Date(Time Analyzed 08/01/2005 18:36 Sample Matrix (as Received) Soil Analysis Confirmed No Dilution Factor 1 Percent Moisture 23.0 Result Units _ mglkg Total PHS 52 U (Surr) C -39 (° %) 43 J1 (Surr) OTP ( %) 66 am An am MR an am U = Undetected. The value preceeding the'U' is the RL for the analyte, based on dilution. Results reported on a Dry Wei ht basis, NELAP- FDOH Certification # E83239 Reviewed by Quality Control Report for Spike /Spike Duplicate Analysis Quality Control Limits Petroleum Hydrocarbons Matrix: Sail Analysis Date: 08/0112005 Lab Sample ID: 205070222 -3 Preparation Date: 08101/2005 s QC Batch ID: 200507FLR0001 Method: FL -PRO Spike Units: mglkg Analyst: DN RPD Spike MSD 50 Spike Sample Spike Percent MSD Percent Analyte Amount Result Result Recovery Result Recovery RPD (Surr) C-39 100,0 0.0 21.0 21 31.0 31 38 ' (Surr) OTP 100.0 0.0 98.0 98 148.0 148 41 Total PHS 50.0 0.0 44.3 89 66.6 133 40 ' " PC &B Environmental Laboratories, Inc. LabForms LIMS Quality Control Limits Lower Upper Analyte Limit Limit RPD SS C-39 50 118 25 SS_OTP 42 120 25 Total PHS 40 204 25 " PC &B Environmental Laboratories, Inc. LabForms LIMS PC &B Environmental Laboratories, Inc. 210 Park Road Oviedo, FL 32765.8801 PHONE: 407- 359 -7194 FAX: 407 - 359 -7197 Report of Analysis EDB /DBCP Lab Reference Number 205070222 -1 Client Sample ID TMW -1 Date/Time Sampled 07/2012005 Date/Time Extracted 07/2712005 DatelTime Analyzed 07/27/2005 15 :52 Sample Matrix (as Received) Water Analysis Confirmed No Dilution Factor 1 Result Units ug /I Ethylene dibromide (EDB) 0.01 U 1,2- Dibromo- 3- chloropropane 0.02 U (Surr) BFB ( °/u} 86 .M1 CLIENT NAME: Ardaman & Associates PROJECT NAME: SEB Airport PROJECT NUMBER: 05 5426 DATE RECEIVED: 07/26/2005 ANALYTICAL PROTOCOL: EPA 5441504.1 U = Undetected. The value preceeding the 'U' is the RL for the anal e, based an dilution. Results reported on a Wet Weight basis. NELAP- FDOH Certification # E83239 Reviewed by: Quality Control Report for Spike Analysis EDB /DBCP Matrix: Water Analysis Date: 07/27/2005 Lab Sample ID: 205070198 -2 Preparation Date: 07127/2005 QC Batch ID: 200507EDB007 Method: EPA 504 Spike Units: ug /I Analyst: RM Lower Upper Spike Sample Spike Percent Control Control Analyte Amount Result Result Recovery Limit Limit (Surr) BFB 100.0 0.0 86.0 86 65 139 Ethylene dibromide (EDB) 1.00 0.00 0.80 80 62 140 1,2- Dibromo- 3- chloropropane 1.0 0.0 0.8 80 52 145 PC &B Environmental Laboratories, Inc. LabForms LIMS PC &B Environmental Laboratories, Inc. Report of Analysis CLIENT NAME: Ardaman & Associates 210 Park Road PROJECT NAME: SEB Airport Oviedo„ FL 32765 -8801 PROJECT NUMBER: 05 5426 PHONE: 407- 359 -7194 DATE RECEIVED: 0712612005 Lab Reference Number 205070222 -1 Client Sample ID TMW -1 Daterrime Sampled 0712012005 —Sample Matrix as Received) Water EPA 60101200.7 Lead, Totai ugll 4 .. am U = Undetected. The value Reviewed by am the V is the RL Far the analyte. Results reported on a Wet Weight basis. 4 NELAP- FDOH Certification # E83239 Quality Control Report for Spike Analysis INORGANICS Lower Upper r Spike Sample Spike Percent Control Control Analyte Amount Result Result Recovery Limit Limit Method EPA 6010200.7 QC Batch. 200507RC158 Sample ID 205070229.1 Date Prep: 07127/20G5 Date Anal: 072712005 Analyst: GG Lead, Total 100 ugll 0 99 99 80 170 PC &B Environmental Laboratories, Inc. LabForms LIMS G � � 1 � r s w v 4 M M W fU a O 0 co �I 0) (.n A. 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